Hebei Orient Rubber & Plastic co., LTD
Email:orientflex@orientrubber.com
Phone:0086-311-68008301
Skype:orientrubber
Address:No.298 Zhonghua North Street ShiJiaZhuang, HeBei, China.
Hose products are
widely used in machinery, automobile, construction, chemical, transportation,
medicine, agriculture and other industries. Various hoses have different
requirements.
In general, according to the application requirements can be divided into
ordinary hose, referring to the conveying air at room temperature, water or
other inert gases, other neutral liquid fabric hose; special hose main oil
hose, acid hose, heat-resistant hose, hydraulic hose, mud injection hose,
automatic brake hose, diving hose, special hose food, medicine and so on with a
hose. The various requirements of different hose recipe is not the same. In
addition to food, medical special hose and hose generally do not use black
light outside, without exception were applied black, or carbon black and other
inorganic fillers and used as a reinforcing filler system.
Oil hose as a hose in addition to meet basic mechanical properties
requirements, notably oil to meet performance requirements. The oil resistance
of the rubber vulcanizate refers to the ability of the effect of anti-oil,
i.e., when a variety of rubber products with long-term contact with fluid, the
fluid can penetrate into the expansion of the rubber manipulation (or increase
in size), or oil medium It can be extracted soluble complexing agent (such as
plasticizers) from vulcanized rubber, resulting in vulcanized rubber shrinkage
(or volume reduction). Used oil has oil, hydraulic oil, engine oil, fuel oil
and other oils. Evaluation of oil is usually measured vulcanized rubber in the
oil, the volume (or mass) after a predetermined temperature and time of
immersion of the percentage change in the standard test oil, or the percentage
change in hardness (or difference).
Vulcanized rubber oil resistance depends mainly on the rubber
vulcanization system and chemical properties of oil. Oil usually non-polar, so
rubber containing a polar group such as nitrile rubber, chloroprene rubber, a
larger difference between the two polar, nonpolar oils have good stability.
Furthermore, the rubber vulcanization system has an important impact on
improving oil resistance.
In general, oil resistance with increasing crosslinking
density of the network structure to reduce the free volume of the oil leaving
the infiltration and diffusion difficulties, thereby increasing the oil
resistance. In addition, the type of crosslinks also related to peroxide-cured
or effective sulfur vulcanized rubber (eg nitrile rubber) than the general
sulfur vulcanization system of rubber oil resistance is better. Of carbon black
as a reinforcing agent in terms of filling, although no direct impact, but the
indirect effects of oil, mainly in two aspects, one is to increase the use of
carbon black fraction and reduce the volume fraction of the rubber compound
rubber can be improve oil resistance of rubber, on the other hand are filled
with active carbon black, and increase the activity of the higher crosslink
density of the vulcanized rubber, enhance the binding force between rubber
molecules, thus increasing the resistance to oil penetration and swelling
capacity, Therefore, to improve the performance of oil and rubber products.
So if the oil resistance point of view, in the rubber
compound filled with carbon black particles, the higher the activity. However,
in practical applications, often require oil hose also be used in high
temperature conditions, so at the same time also requires both oil heat, it is
necessary to consider the actual conditions of use and processing of products,
often take a hard high HAF and soft generic, fast extruding semi-reinforcing
carbon black and other methods used. Soft black varieties processing
performance is relatively good, especially out of the hose, such as using a
particle centered structure slightly faster extrusion (N550) carbon black
products are dimensionally stable, smooth surface, is often used in a variety
of carbon black one.